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  <record>
    <language>eng</language>
          <publisher>Oriental Scientific Publishing Company</publisher>
        <journalTitle>Biosciences Biotechnology Research Asia</journalTitle>
          <issn>0973-1245</issn>
            <publicationDate>2016-06-11</publicationDate>
    
        <volume>11</volume>
        <issue>Spl.Edn.2</issue>

 
    <startPage>93</startPage>
    <endPage>108</endPage>

	 
      <doi>10.13005/bbra/1445</doi>
        <publisherRecordId>11933</publisherRecordId>
    <documentType>article</documentType>
    <title language="eng">Rare Earth Elements as Geochemical Criteria of the Oil-bearing Capacity of the Formations</title>

    <authors>
	 


      <author>
       <name>Klimenty S. Tsoy</name>

 
		
	<affiliationId>1</affiliationId>
      </author>
    

	

	

	


	


	
    </authors>
    
	    <affiliationsList>
	    
		
		<affiliationName affiliationId="1">Federal State Autonomous Educational Institution of Higher Education , “The Tomsk National Research State University” 36, Lenina Av., Tomsk, Russia, 634050.</affiliationName>
    

		
		
		
		
		
	  </affiliationsList>






    <abstract language="eng">The REE studies in the formations of clastic and carbonate type with the presence
of hydrocarbon oil and gas showed that components of bitumen and oil accordingly did
not only have a significant impact on REE fractionation between the formations of oil
and gas deposits, but also became the main differentiation cause (factor) in the behavior
of the individual lanthanides being a part of REE of the formations’ mineral and organic
complexes. As exemplified by the study of the South Pyzhinskaya 1 parametric well’s
section (Western Siberia), the 12th Kokdumalak oil and gas deposits’ well (Uzbekistan)
and the Krapivinskoye oil and gas field (Western Siberia), there were shown the variations
of the full REE composition spectra. There were specified the differences in the behavior
of individual lanthanides in REE composition of formations and their factions - the acid
extract (1.8% HCl), taken as a movable mineral complex (MMC), and the organic part of
the alcohol-benzene mixture (OP ABM). Reasons for fractionation and differentiation in
the lanthanide behavior are considered from the standpoint of the oil and gas
hydrocarbons of petroleum fluids impact on the redox conditions of the environment,
impact of their stabilizing properties on the lanthanide valence states and REE
isomorphism. The results of the formation studies taken from the South Pyzhinskaya 1
well were compared with the changes in the isotopic composition of carbon and oxygen in
the well section. There was provided a comparison of the ratios Ce4+/Ce3+ in various
samples of insoluble residue 1.8% HCl and OP ABM, as well as the ratio of Eu2+/Eu3+ in oil
from the zone of OM generation. As a result, there were revealed significant differences in
the REE behavior within oil and gas deposits, enabling to interpret REE as geochemical
criteria of the oil-bearing formations.</abstract>

    <fullTextUrl format="html">https://www.biotech-asia.org/vol11_nospl_edn2/rare-earth-elements-as-geochemical-criteria-of-the-oil-bearing-capacity-of-the-formations/</fullTextUrl>



      <keywords language="eng">
        <keyword>Formation fractions; Differentiation in the lanthanide behavior within the REE composition; variations of carbon and oxygen isotopic composition; the ratio of Ce4+/Ce3+ and Eu2+/Eu3+; valence; isomorphism</keyword>
      </keywords>

  </record>
</records>